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KTP

(Potassium Titanyl Phosphate)

Potassium Titanyl Phosphate (KTP) has the following exceptional properties that make it a very important nonlinear crystal:

  • Wide angular bandwidth and small walk-off angle
  • Broad temperature and spectral bandwidth
  • Large nonlinear optical coefficient
  • High electro-optic coefficient and low dielectric constant
  • Large figure of merit
  • Nonhydroscopic, chemically and mechanically stable
  • High thermal conductivity
  • Moisture free
  • Minimum mismatch gradient
  • Low cost compare with BBO and LBO
 
 
 

KTP is a positive biaxial crystal, with the principal axes X, Y, and Z (nz>ny>nx) parallel to the crystallographic axes a, b, and c, respectively. 

   
     

Physical Properties
Crystal structure
Orthorhombic, space group Pna21,point group mm2
Cell parameters
a=6.404Å, b=10.616Å, c=12.814Å, Z=8
Melting point
1172°C incongruent
Curie point
936°C
Mohs hardness
»5
Density
3.01 g/cm3
Color
colorless
Hygroscopic susceptibility
no
Specific heat
0.1643 cal/g°C
Thermal conductivity
0.13 W/cm/°K
Electrical conductivity
3.5x10-8 s/cm (c-axis, 22°C, 1KHz)
  Linear Optical Properties
Transmitting range
350 nm - 4500 nm

Refractive indices

1064nm

532nm

 nx           ny          nz

1.7377   1.7453   1.8297

1.7780   1.7886   1.8887

Sellmeier equations (l in mm)
nx2=3.0065+0.03901/(λ2-0.04251)-0.01327λ2
ny2=3.0333+0.04154/(λ2-0.04547)-0.01408λ2
nz2=3.3134+0.05694/(λ2-0.05658)-0.01682λ2
Therm-optic coefficients
dnx/dT=1.1x10-5/°C, dny/dT=1.3x10-5/°C, dnz/dT=1.6x10-5/°C
Absorption coefficient
α < 0.1%/ cm @1064nm and 532nm
Nonlinear Optical Properties
Phase matchable SHG range
497 - 1800nm
Nonlinear optical coefficients

d31=6.5pm/v, d32=5pm/v, d33=13.7pm/v, d24=7.6pm/v, d15=6.1pm/v

Effective nonlinearity expressions

deff(II)≈(d24-d15)sin2φsin2θ-(d15sin2φ + d24cos2φ)sinθ

For type II SHG of a Nd:YAG laser at 1064nm

PM angle: θ=90°, φ=23.5°
Effective SHG coefficient:  deff≈8.3xd36(KDP)
Angular acceptance: 20 mrad-cm
Temperature acceptance: 25°C-cm
Spectral acceptance: 5.6 Å -cm
Walk-off angle: 4.5 mrad
Optical damage threshold: > 450MW/cm2 at 1064nm, 10ns, 10Hz
Electro-optic coefficients
Low frequency (pm/V)  
High frequency (pm/V)
r13
9.5
8.8
r23
15.7
13.8
r33
36.3
35.0
r51
7.3
6.9
r42
9.3
8.8
Dielectric constant
εeff=13

 Applications

  • Frequency doubling (SHG) of Nd-doped lasers for green/red outputs.
  • Frequency mixing (SFM) of Nd laser and diode laser for blue outputs.
    Parametric sources (OPG, OPA and OPO) for 600nm-4500nm tunable outputs.
    E-O modulators, optical switches, directional couplers.
  • Optical waveguides for integrated NLO and E-O devices.
Applications for SHG and SFG of Nd:lasers

KTP is used commonly as one of the doublers of Nd:YAG lasers and other Nd-doped lasers. The following Table lists its major NLO properties for frequency-doubling of Nd:YAG laser.

PM angle

θ=90°,φ=23.5°

Effective SHG coefficient

deff≈ 8.3xd36(KDP)

Angular acceptance

20 mrad-cm

Temperature acceptance

25°C-cm

Spectral acceptance

5.6 Å-cm.

Walk-off angle

4.5mrad

Optical damage threshold

> 450MW/cm2 at 1064nm, 10ns, 10Hz

With KTP, extra- and intra-cavity frequency doubled Nd:laser has become a preferred green laser source for R&D, medical, industrial and commercial applications. By using extracavity KTP SHG, over 80% conversion efficiency and 700mJ green laser were obtained with a 900 mJ injection-seeded Q-switched Nd:YAG laser.

Applied to diode-pumped Nd:laser, KTP is a basic NLO crystal for the construction of compact visible solid state laser systems. Recent advances in intracavity-doubled Nd:YVO4 and Nd:YAG lasers have increased the demand for compact green lasers used in display, construction, optical disk and laser printer. Over 200 mw TEM00 green outputs are available from LD pumped Nd:YVO4 and Nd:YAG lasers and 3 W TEM00, mode-locked green laser was generated by intracavity SHG in a 5.3 W mode-locked diode-laser pumped Nd:YAG laser. Moreover, 2.5mW green light was obtained from 50mW LD pumped and intracavity doubled Nd:YVO4 mini-lasers with a 9mm long cavity.

KTP is also a powerful crystal for SHG and SFG of laser with wavelength from about 1μm to 3.4μm. The SHG phase-matching angle and effective SHG coefficients (deff) of KTP in XY plane (0.9μm to 1.08μm) and XZ plane (1.1 μm to 3.3 μm) are showed as the figtures. Although KTP cut in YZ plane can be phase-matched for SHG of 1μm to 3.45μm, it is seldom used in practices because of the low deff.

Type ll SHG in XY Plane

Type ll SHG in XZ Plane

OPO Pumped at 1064 nm

  OPG, OPA and OPO

As an efficient OPO crystal pumped by the fundamental and second harmonics of a Nd:YAG or Nd:YLF laser, KTP plays an important role in parametric sources for tunable output from visible (0.6μm) to mid-IR (4.5μm). The phase-matching angles and effective NLO coefficient for OPO/OPA pumped at 532 nm and 1064 nm in XZ plane are showed as following figures. NCPM KTP OPO pumped by 1064nm, the signal output is around eye safe wavelength, find applications in eye-safe devices. The OPO/OPA in XY and YZ is seldom employed because of their low effective nonlinear coefficients and other limitation. 

KTP's OPO results in stable, continuous outputs of femtosecond pulse of 108 Hz repetition rate and miliwatt average power levels in both signal and idler outputs. KTP's OPO pumped by a 1064nm Nd:laser has generated above 66% conversion efficiency for degenerate conversion from 1064 to 2120 nm.

The recently developed new application is the non-critical phase-matched (NCPM) KTP OPO/OPA pumped by the tunable lasers such as Ti:Sapphire, Alexandrite and Cr:LiSrAlF6 (see right figure). The NCPM KTP OPO keeps the KTP crystal fixed in X-axis and tunes the pumping wavelength. If a tunable Ti:Sapphire laser is used as a pumping source (0.7μm to 1 μm), the output can cover the wavelength range from 1.04μm to 1.45μm (signal) and from 2.15μm to 3.2μm (idler). Due to the favorable NLO properties of NCPM KTP, as high as 45% conversion efficiency was obtained with narrow output bandwidth and good beam quality.

Quasi-Phase-Matched Waveguide

Recently, type II SHG conversion efficiency of 20% was achieved by quasi-phase matched waveguide doubler, in which the phase mismatch from one section is balanced against a phase mismatch of the opposite sign from a second section. Furthermore, segmented KTP waveguides have been applied to type I quasi-phase-matchable SHG of 0.76-0.96μm for tunable Ti:Sapphire laser and directly doubled diode laser for 0.43-0.40μm output. Conversion efficiency in excess of 70% has been obtained.

NCPM KTP for OPO

Efficiency of KTP elements in OPO 1064 - 1570 nm

 

The recently developed new application is the non-critical phase-matched (NCPM) KTP OPO/OPA application. The NCPM KTP OPO keeps the KTP crystal fixed in X-axis and tunes the pumping wavelength. If 1064nm pumping source, the output will be at 1.57μm (signal) and 3.3μm (idler). Due to the favorable NLO properties of NCPM KTP, as high as 45% conversion efficiency was obtained with narrow output bandwidth and good beam quality.

 DPM Crystal for Green Laser Pointer

  Nd:YVO4+KTP for Green Laser Pointer

The most outstanding advantage of DPSS laser is its compact package, especially for Green Laser Pointer. CORSTEC supply which combine Nd:YVO4 crystal with KTP crystal, resulting in efficient, ultra-compact, diode pumped laser devices emitting the green laser. It greatly reduces your material cost and enhances assembling efficiency.

Diode pumped Nd:YVO4+KTP green laser pointer

Nd:YVO4 (mm3)
KTP (mm3)
Pump Power
Output
2x2x1
2x2x3
150mW
>1mW
3x3x1
3x3x5
500mW
>20mW

Coating: S1: R>99.8% @1064 nm, R<5% @808 nm;S2: R>99.8% @1064 nm, R<5% @532 nm

Standard Products

Part No.
Nd:YVO4
KTP
PDM01
2x2x1
2x2x3mm
PDM02
2x2x1
2x2x5mm
PDM03
3x3x1
3x3x5mm
Specifications
Wavefront distortion
less than λ/8 @ 633nm
Dimension tolerance
(W ± 0.1mm) x (H ± 0.1mm) x (L + 0.2mm/-0.1mm)
Clear aperture
> 90% central area
Flatness
λ/8 @ 633nm
Scratch/Dig
10/5 to MIL-O-13830A
Parallelism
better than 20 arc seconds
Perpendicularity
5 arc minutes
Angle tolerance
Δθ <± 0.3°, Δφ< ±0.3°

Warranty

  • More than 200,000pcs/year ability
  • High inside quality without any defection.
  • Large crystal size up to 20x20x40mm3
  • Low absorption at 532nm
  • Large quantity standard products in-stock
  • Fast delivery. (1-2 weeks ARO )
  • Strict quality control.
 
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